Yes, devious is a Scrabble word!
...and is worth 11 points in Scrabble, and 13 points in Words with Friends
devious
Adjective
1. Indirect in departing from the accepted or proper way; misleading
2. Characterized by insincerity or deceit; evasive
3. Deviating from a straight course
What Scrabble words can I make with the letters in devious?
6 Letter Words
5 Letter Words
4 Letter Words
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3 Letter Words
2 Letter Words