Yes, group is a Scrabble word!
...and is worth 8 points in Scrabble, and 11 points in Words with Friends
group
Verb
1. Arrange into a group or groups
2. Form a group or group together
Noun
1. Any number of entities (members) considered as a unit
2. (chemistry) two or more atoms bound together as a single unit and forming part of a molecule
3. A set that is closed, associative, has an identity element and every element has an inverse
What Scrabble words can I make with the letters in group?
4 Letter Words
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3 Letter Words
2 Letter Words