Yes, jives is a Scrabble word!
...and is worth 15 points in Scrabble, and 18 points in Words with Friends
jives
Verb
1. Dance to jive music; dance the jive
Noun
1. A style of jazz played by big bands popular in the 1930s; flowing rhythms but less complex than later styles of jazz
What Scrabble words can I make with the letters in jives?
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Words that can be created with an extra letter added to jives:
R:jivers