Yes, twill is a Scrabble word!
...and is worth 8 points in Scrabble, and 10 points in Words with Friends
twill
Verb
1. Weave diagonal lines into (textiles)
Noun
1. A weave used to produce the effect of parallel diagonal ribs
2. A cloth with parallel diagonal lines or ribs
What Scrabble words can I make with the letters in twill?
4 Letter Words
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3 Letter Words
2 Letter Words