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Yes, vow is a Scrabble word!
...and is worth 9 points in Scrabble, and 10 points in Words with Friends
1. Make a vow; promise
2. Dedicate to a deity by a vow
1. A solemn pledge (to oneself or to another or to a deity) to do something or to behave in a certain manner
What Scrabble words can I make with the letters in vow?
2 Letter Words