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Yes, na is a Scrabble word!
...and is worth 2 points in Scrabble, and 3 points in Words with Friends
1. A silvery soft waxy metallic element of the alkali metal group; occurs abundantly in natural compounds (especially in salt water); burns with a yellow flame and reacts violently in water; occurs in sea water and in the mineral halite (rock salt)
What Scrabble words can I make with the letters in na?
2 Letter Words