Yes, item is a Scrabble word!
...and is worth 6 points in Scrabble, and 7 points in Words with Friends
item
Adverb
1. (used when listing or enumerating items) also
Noun
1. A distinct part that can be specified separately in a group of things that could be enumerated on a list
2. A small part that can be considered separately from the whole
3. A whole individual unit; especially when included in a list or collection
4. An isolated fact that is considered separately from the whole
5. An individual instance of a type of symbol
What Scrabble words can I make with the letters in item?
4 Letter Words
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3 Letter Words
2 Letter Words