Yes, naif is a Scrabble word!
...and is worth 7 points in Scrabble, and 8 points in Words with Friends
naif
Adjective
1. Marked by or showing unaffected simplicity and lack of guile or worldly experience
Noun
1. A naive or inexperienced person
What Scrabble words can I make with the letters in naif?
4 Letter Words
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3 Letter Words
2 Letter Words