Yes, tier is a Scrabble word!
...and is worth 4 points in Scrabble, and 4 points in Words with Friends
tier
Noun
1. A relative position or degree of value in a graded group
2. Any one of two or more competitors who tie one another
3. A worker who ties something
4. Something that is used for tying
5. One of two or more layers one atop another
What Scrabble words can I make with the letters in tier?
4 Letter Words
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3 Letter Words
2 Letter Words