Yes, pean is a Scrabble word!
...and is worth 6 points in Scrabble, and 8 points in Words with Friends
pean
Noun
1. (ancient Greece) a hymn of praise (especially one sung in ancient Greece to invoke or thank a deity)
2. A formal expression of praise
What Scrabble words can I make with the letters in pean?
4 Letter Words
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3 Letter Words
2 Letter Words